Allene epoxidation. Oxidative cyclizations of allenyl alcohols.1

✍ Scribed by Jack K. Crandall; David J. Batal

• Book ID: 104216712
• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 217 KB
• Volume: 29
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)80610-3

✦ Synopsis

Summarv: The dimethyldioxirane oxidation of various allenic alcohols yields highly functionalized tetrahydrofuran and tetrahydropyran derivatives via intramolecular nucleophilic addition of the hydroxy group to an intermediate allene diepoxide.