Allene epoxidation. Oxidative cyclizatio
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Jack K. Crandall; David J. Batal
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Article
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1988
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Elsevier Science
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French
β 217 KB
Summarv: The dimethyldioxirane oxidation of various allenic alcohols yields highly functionalized tetrahydrofuran and tetrahydropyran derivatives via intramolecular nucleophilic addition of the hydroxy group to an intermediate allene diepoxide.