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Allene epoxidation. Oxidative cyclizations of allenyl acids

✍ Scribed by Crandall, Jack K.; Rambo, Elisa


Book ID
126937342
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
236 KB
Volume
55
Category
Article
ISSN
0022-3263

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Allene epoxidation. Oxidative cyclizatio
✍ Jack K. Crandall; David J. Batal πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 217 KB

Summarv: The dimethyldioxirane oxidation of various allenic alcohols yields highly functionalized tetrahydrofuran and tetrahydropyran derivatives via intramolecular nucleophilic addition of the hydroxy group to an intermediate allene diepoxide.