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Preparation of Homoallylic Alcohols by Nickel-Catalyzed Cyclizations of Allenyl Aldehydes.

โœ Scribed by John Montgomery; Minsoo Song

Publisher
John Wiley and Sons
Year
2003
Weight
129 KB
Volume
34
Category
Article
ISSN
0931-7597

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Nickel-Catalyzed Homoallylation of Aldeh
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โœ Masanari Kimura; Akihiro Ezoe; Shuji Tanaka; Yoshinao Tamaru ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 94 KB ๐Ÿ‘ 1 views

By virtue of their high polarity, a wide variety of allylic metal and metalloid (e.g., B, Si, Sn) complexes can serve as nucleophilic reagents toward carbonyl compounds; [1] some allylations can be successfully performed even in the presence of water under Barbier conditions. [2] On the other hand,