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Nickel-Catalyzed Homoallylation of Aldehydes in the Presence of Water and Alcohols

โœ Scribed by Masanari Kimura; Akihiro Ezoe; Shuji Tanaka; Yoshinao Tamaru

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
94 KB
Volume
40
Category
Article
ISSN
0044-8249

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Nickel-Catalyzed Homoallylation of Aldeh
Nickel-Catalyzed Homoallylation of Aldehydes in the Presence of Water and Alcohols
โœ Masanari Kimura; Akihiro Ezoe; Shuji Tanaka; Yoshinao Tamaru ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 94 KB

By virtue of their high polarity, a wide variety of allylic metal and metalloid (e.g., B, Si, Sn) complexes can serve as nucleophilic reagents toward carbonyl compounds; [1] some allylations can be successfully performed even in the presence of water under Barbier conditions. [2] On the other hand,