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Preparation of Homoallylic Alcohols by Nickel-Catalyzed Cyclizations of Allenyl Aldehydes

โœ Scribed by Montgomery, John; Song, Minsoo

Book ID
126960286
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
58 KB
Volume
4
Category
Article
ISSN
1523-7060

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โœ Masanari Kimura; Akihiro Ezoe; Shuji Tanaka; Yoshinao Tamaru ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 94 KB ๐Ÿ‘ 2 views

By virtue of their high polarity, a wide variety of allylic metal and metalloid (e.g., B, Si, Sn) complexes can serve as nucleophilic reagents toward carbonyl compounds; [1] some allylations can be successfully performed even in the presence of water under Barbier conditions. [2] On the other hand,