Alkyliminophosphorsäuretrihalogenide, 1. Mitt.: Halogenaustausch zwischen (CH3NPCl3)2und (CH3NPF3)2
✍ Scribed by K. Utvary; W. Czysch
- Book ID
- 104999554
- Publisher
- Springer Vienna
- Year
- 1969
- Tongue
- English
- Weight
- 337 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0026-9247
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📜 SIMILAR VOLUMES
Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate
Excess molar enthalpies at the temperature 298.15 K were measured for CH2)n-2CH3}, (n = 10, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-Chao, UNIFAC I, and UNIFAC II models.
The title compound has been prepared in good yield by the reaction of [Me 2 GaOMe] 3 (Me = CH 3 ) with HP(SiMe 3 ) 2 in toluene (ratio 1 : 1,1) and purified by crystallization from pentane or toluene, respectively. This organogallium compound forms (Ga±P) 3 ring skeletons with one Ga±P(SiMe 3 ) 2 ±G
## Excess molar volumes at CH2 )n-2CH3}, (n= 10 or n = 12), and {xCH3(CH2)3CH2Cl + (1x)CH3(CH2)n-2CH3}, (n= 10 or n = 12), were determined using a densimeter Anton Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternar