The title compound has been prepared in good yield by the reaction of [Me 2 GaOMe] 3 (Me = CH 3 ) with HP(SiMe 3 ) 2 in toluene (ratio 1 : 1,1) and purified by crystallization from pentane or toluene, respectively. This organogallium compound forms (Ga±P) 3 ring skeletons with one Ga±P(SiMe 3 ) 2 ±G
Die He(I)-Photoelektronenspektren von (CH3)2PSCH3, (CH3)2AsSCH3, (CH3)2AsSeCH3 und (CH3)2PSeCH31)
✍ Scribed by Böm, Michael C. ;Eckert-Maksić, Mirjana ;Gleiter, Rolf ;Grobe, Joseph ;Le Van, Duc
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1981
- Tongue
- English
- Weight
- 350 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0009-2940
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The thermal decomposition of [Me 2 Ga±N( i Bu)SnMe 3 ] 2 (prepared by the reaction of [Me 2 SnN i Bu] 3 with GaMe 3 in a 1 : 3 molar ratio) in an evacuated, sealed tube at 160 °C forms [MeGaN i Bu] 6 in high yield and SnMe 4 . Mass, 1 H and 13 C NMR as well as some IR and Raman spectroscopic data ar
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