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Alkoxylation of hydridophosphorane. II. Reaction of hydridophosphorane with benzenesulphenic esters

✍ Scribed by Lunzu Liu; Guowei Li; Mingzhi Huang; Ruzhen Cao; Shukui Zhang

Book ID
102227878
Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
312 KB
Volume
4
Category
Article
ISSN
1042-7163

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✦ Synopsis

The spirophosphorane 4 underwent reaction with a series of benzene-su,?phenic esters 3 to give the corresponding isolable alkoxyphosphoranes. The reactivities of benzenesulphenic esters 3 in this reaction were seen to be dependent on steric hindrance of the R groups. The yields of alkoxyphosphoranes were influenced by the reaction temperature. The probable mechanism was suggested in terms of experimental observations.

πŸ“œ SIMILAR VOLUMES

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