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The Reactions of Hydridophosphorane with Vilsmeier Reagents

✍ Scribed by Dingquan Qian; Xingzhong Zeng; Xiaodong Shi; Ruzhen Cao; Lunzu Liu

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
164 KB
Volume
8
Category
Article
ISSN
1042-7163

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✦ Synopsis

Reactions of hydridophosphorane 3 with Vilsmeier reagents, HCONR 1 R 2 /POCl 3 , afford novel N,N-disubstituted amino bisphosphoranyl methanes4. The formation of 4 might occur via the intermediate 5, which then reacts further with excess 3.

πŸ“œ SIMILAR VOLUMES

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Reaction of hydridophosphorane 1 with nucleophilic reagents 2 and tetrachloromethane in the presence of triethylamine, according to the Atherton-Todd reaction methodology leads ultimately to the formation of phosphoranes 3 in good yields. A probabLe mechanism has been suggested in terms of experimen

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v