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The Atherton-Todd reaction of hydridophosphoranes

✍ Scribed by Lunzu Liu; Gouwei Li; Xingzhong Zeng; Lanbing Fu; Ruzhen Cao

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
357 KB
Volume
7
Category
Article
ISSN
1042-7163

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✦ Synopsis

Reaction of hydridophosphorane 1 with nucleophilic reagents 2 and tetrachloromethane in the presence of triethylamine, according to the Atherton-Todd reaction methodology leads ultimately to the formation of phosphoranes 3 in good yields. A probabLe mechanism has been suggested in terms of experimental obsewations.

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