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ChemInform Abstract: The Reaction of PhCH2C(O)NR2/P(O)Cl3 with Phosphites and Hydridophosphorane.

✍ Scribed by Wen-Hu Wang; Guo-Yan Xu; Ru-Zhen Cao; Lun-Zu Liu

Publisher: John Wiley and Sons
Year: 2001
Weight: 33 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200110182

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The rate constants of the reactions of ethoxy (C 2 H 5 O), i-propoxy (i-C 3 H 7 O) and npropoxy (n-C 3 H 7 O) radicals with O 2 and NO have been measured as a function of temperature. Radicals have been generated by laser photolysis from the appropriate alkyl nitrite and have been detected by laser-