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AlCl 3 -Promoted Highly Regio- and Diastereoselective [3 + 2] Cycloadditions of Activated Cyclopropanes and Aromatic Aldehydes: Construction of 2,5-Diaryl-3,3,4-trisubstituted Tetrahydrofurans

✍ Scribed by Yang, Gaosheng; Shen, Yue; Li, Kui; Sun, Yongxian; Hua, Yuanyuan


Book ID
120464113
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
994 KB
Volume
76
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Highly Diastereosel
✍ Gopal Sathishkannan; Kannupal Srinivasan πŸ“‚ Article πŸ“… 2012 πŸ› John Wiley and Sons βš– 41 KB πŸ‘ 2 views

Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl 4 -Promoted [3 + 2] Cycloaddition Between Activated Donor-Acceptor Cyclopropanes and Nitriles. -The products are isolated as single cis diastereomers. Using standard imine chemistry, the preparation of useful derivatives such as (VI) is p