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ChemInform Abstract: AlCl3-Promoted Highly Regio- and Diastereoselective [3 + 2] Cycloadditions of Activated Cyclopropanes and Aromatic Aldehydes: Construction of 2,5-Diaryl-3,3,4-trisubstituted Tetrahydrofurans.

✍ Scribed by Gaosheng Yang; Yue Shen; Kui Li; Yongxian Sun; Yuanyuan Hua


Publisher
John Wiley and Sons
Year
2011
Weight
56 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Diastereosel
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Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl 4 -Promoted [3 + 2] Cycloaddition Between Activated Donor-Acceptor Cyclopropanes and Nitriles. -The products are isolated as single cis diastereomers. Using standard imine chemistry, the preparation of useful derivatives such as (VI) is p