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Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl 4 -Promoted [3 + 2] Cycloaddition between Activated Donor–Acceptor Cyclopropanes and Nitriles

✍ Scribed by Sathishkannan, Gopal; Srinivasan, Kannupal

Book ID
126173021
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
869 KB
Volume
13
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Highly Diastereosel
ChemInform Abstract: Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl4-Promoted [3 + 2] Cycloaddition Between Activated Donor—Acceptor Cyclopropanes and Nitriles.
✍ Gopal Sathishkannan; Kannupal Srinivasan 📂 Article 📅 2012 🏛 John Wiley and Sons ⚖ 41 KB 👁 2 views

Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl 4 -Promoted [3 + 2] Cycloaddition Between Activated Donor-Acceptor Cyclopropanes and Nitriles. -The products are isolated as single cis diastereomers. Using standard imine chemistry, the preparation of useful derivatives such as (VI) is p