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Additions and Corrections - Electron Spin Resonance of Group IV Organometallic Alkyl Radicals in Solution

โœ Scribed by Krusic, Paul J.; Kochi, Jay K.

Book ID
127118314
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
129 KB
Volume
92
Category
Article
ISSN
0002-7863

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Electron Spin Resonance of ฮฑ-(Alkoxycarb
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โœ Wu Lung-min; Hanns Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 502 KB

High-resolution ESR. spectra of the radicals CH2COOR, CH3CHCOOR and (CH3)ZCCOOR with R = CH3, CH2CH3, CH (CH,), and C (CH,), in liquid solution confirm planar energy-minimum structures with substantial barriers to internal rotation about the C, CO-bonds (-40 kJ/mol) and partial n-electron delocaliza