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Electron Spin Resonance Spectra of Unsaturated Radicals in Irradiated Tetra-alkyl Ammonium Halides

✍ Scribed by TENCH, A. J.


Book ID
109627953
Publisher
Nature Publishing Group
Year
1963
Tongue
English
Weight
218 KB
Volume
198
Category
Article
ISSN
0028-0836

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High-resolution ESR. spectra of the radicals CH2COOR, CH3CHCOOR and (CH3)ZCCOOR with R = CH3, CH2CH3, CH (CH,), and C (CH,), in liquid solution confirm planar energy-minimum structures with substantial barriers to internal rotation about the C, CO-bonds (-40 kJ/mol) and partial n-electron delocaliza