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Electron spin resonance spectra and structures of phosphoranyl radicals in solution

✍ Scribed by Krusic, Paul J.; Mahler, Walter; Kochi, Jay K.


Book ID
127253096
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
978 KB
Volume
94
Category
Article
ISSN
0002-7863

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Electron spin resonance of a stereochemi
✍ Paul J. Krusic; Paul Meakin πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 441 KB

Evidence based on temperature dependent ESR line shape changes is presented for the mobility of thdfigarrds in the phosphorus-centered radical (CHa)sCOPHs rcsu!ting by addirion of a tert-butosy radical to phosphine CNDO calculations favor for the slow exchange limit a trigonal bipyramidal structure