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Electron spin resonance of organosilyl radicals in solution

โœ Scribed by Krusic, Paul J.; Kochi, Jay K.


Book ID
126125860
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
411 KB
Volume
91
Category
Article
ISSN
0002-7863

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High-resolution ESR. spectra of the radicals CH2COOR, CH3CHCOOR and (CH3)ZCCOOR with R = CH3, CH2CH3, CH (CH,), and C (CH,), in liquid solution confirm planar energy-minimum structures with substantial barriers to internal rotation about the C, CO-bonds (-40 kJ/mol) and partial n-electron delocaliza