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Additions and Corrections - A Stereocontrolled Synthesis of the (±) Djerassi-Prelog Lactonic Acid

✍ Scribed by Stork, Gilbert; Nair, Vijay


Book ID
126093249
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
90 KB
Volume
102
Category
Article
ISSN
0002-7863

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A synthesis of (+)-Prelog-Djerassi Lacto
✍ Steven D. Hiscock; Peter B. Hitchcock; Philip J. Parsons 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 852 KB

A new approach to the synthesis of Prelog-Djerassi Lactonic acid (1) is reported. A key step in this synthesis involves an lreland-Claisen rearrangement/silicon-mediated fragmentation sequence to provide the carbon framework in (1).