๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

A stereocontrolled synthesis of the (.+-.) Djerassi-Prelog lactonic acid

โœ Scribed by Stork, Gilbert; Nair, Vijay

Book ID
126202292
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
259 KB
Volume
101
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

A synthesis of (+)-Prelog-Djerassi Lacto
A synthesis of (+)-Prelog-Djerassi Lactonic acid
โœ Steven D. Hiscock; Peter B. Hitchcock; Philip J. Parsons ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 852 KB

A new approach to the synthesis of Prelog-Djerassi Lactonic acid (1) is reported. A key step in this synthesis involves an lreland-Claisen rearrangement/silicon-mediated fragmentation sequence to provide the carbon framework in (1).

Total synthesis of (+)-prelog-djerassi l
Total synthesis of (+)-prelog-djerassi lactonic acid
โœ Minoru Isobe; Yoshiyasu Ichikawa; Toshio Goto ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

Optically active Prelog-Djerassi Lactonic Acid i was synthesized from D-glucal; the crucial point being the elaboration of the carboxylic group as shown in eq. 1 and 2 which involve the sequential process [i] asymmetric addition of methyl anion onto the hetero-olefin 2, [ii] trapping