Addition reactions of malonic nitriles with alkanethiol in aqueous solution
✍ Scribed by François Raulin; Suzanne Bloch; Gérard Toupance
- Book ID
- 105008479
- Publisher
- Springer Netherlands
- Year
- 1977
- Tongue
- English
- Weight
- 392 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1573-0875
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📜 SIMILAR VOLUMES
The Co(NH3) 50Hz3+ ion reacts with malonate to form Co(NH3) 50~CCH2C02H2+ or Co(NH3) 50ZCCHzCOz+, depending on the pH of the reaction solution. The kinetics of this anation reaction have been studied as a function of [H+] for the acidity range 1.5 5 pH 5 6.0 in the temperature range of 60 to 8OoC, t
The Michael reaction of various nitroalkanes 1 with electro-factant, produces better results. Good yields of the products 3 are obtained even with hindered, and functionalized star-philic alkenes 2 can be performed in NaOH (0.025Ϫ0.1 M), without any organic solvent. In many cases the presence of tin