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Reactions of melatonin with radicals in deoxygenated aqueous solution

โœ Scribed by P. Stasica; P. Ulanski; J. M. Rosiak


Publisher
Springer
Year
1998
Tongue
English
Weight
477 KB
Volume
232
Category
Article
ISSN
1588-2780

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๐Ÿ“œ SIMILAR VOLUMES


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The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.

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## Abstract Laser flash photolysis combined with competition kinetics with SCN^โˆ’^ as the reference substance has been used to determine the rate constants of OH radicals with three fluorinated and three chlorinated ethanols in water as a function of temperature. The following Arrhenius expressions