Thermodynamic and kinetic aspects of the reaction of aminoguanidine with malonic acid in acidic aqueous solutions
β Scribed by A. V. Chernysheva; V. M. Chernyshev; P. V. Korolenko; V. A. Taranushich
- Book ID
- 111462556
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2008
- Tongue
- English
- Weight
- 237 KB
- Volume
- 81
- Category
- Article
- ISSN
- 1070-4272
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The Co(NH3) 50Hz3+ ion reacts with malonate to form Co(NH3) 50~CCH2C02H2+ or Co(NH3) 50ZCCHzCOz+, depending on the pH of the reaction solution. The kinetics of this anation reaction have been studied as a function of [H+] for the acidity range 1.5 5 pH 5 6.0 in the temperature range of 60 to 8OoC, t
The reaction between tetrachloroaurate(III) and malonic acidfmalonate ion was studied kinetically over a wide range of temperatures, malonate, hydrogen and chloride ion concentrations at ionic strength 1.0 M. The suggested reaction mechanism consists of a series of substitution reactions during whic