Recently R.S.Neale' ha6 reported that the protonated I-ohloroemines add in good yield8 to oertain substituted olefine,partioularly vinyl chloroderivativee,whereas with unsubstituted olefina the reaotion oocur~ in low yields or doesn't at all.The reaeona adduced for thin
Addition of N,N-dibromosulfonamides to internal olefins: Synthesis of N-sulfonylaziridines
β Scribed by T. A. Foglia; E. T. Haeberer; G. Maerker
- Book ID
- 112776337
- Publisher
- Springer-Verlag
- Year
- 1970
- Tongue
- English
- Weight
- 591 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0003-021X
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π SIMILAR VOLUMES
A novel and efficient microwave-assisted one-step reaction was developed to synthesize chiral N-sulfonylaziridines by the reaction of different chiral amino alcohols and sulfonic chlorides. The newly developed microwave synthetic method has the advantage of reducing the reaction time from 24 to 0.5
Homolytic addition reaction of N-halosulfoximides, i.e., diphenyl-N-chloro sulfoximide(i), diphenyl-N-bromosulfoximide(x), and methylphenyl-N-chlorosulfoximide(,$), to such olefins as tert-butylethylene and cyclohexene was found to afford the corresponding N-alkylated sulfoximides, which are presume