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Addition of alkyl-lithium reagents to 2-alkenyl-1,3-dioxanes

โœ Scribed by M. Kool; G.W. Klumpp


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
227 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœ Jeffrey A. Charonnat; Anna L. Mitchell; Bartholomew P. Keogh ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

The conjugate addition of lithium diorganocupmte reagents to the enol tosylate of 1,2cyclohexanedione has been investigated. The intermediate enolates eliminatepara-toluenesulfiiate ion to generate the alkylated 1,2-dicarbonyl system.