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Diastereoselective Addition of Organozinc Reagents to 2-Alkyl-3-(arylsulfanyl)propanals.

✍ Scribed by Michael Larsson; Elodie Galandrin; Hans-Erik Hoegberg


Publisher
John Wiley and Sons
Year
2005
Weight
46 KB
Volume
36
Category
Article
ISSN
0931-7597

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Enantioselective Addition of Organozinc
✍ Manabu Hatano; Takashi Miyamoto; Kazuaki Ishihara πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 265 KB πŸ‘ 1 views

## Abstract The enantioselective addition of organozinc reagents to aromatic and aliphatic aldehydes **1** gives secondary alcohols **2** with excellent enantioselectivities in high yields through the catalytic use of (__R__)‐3,3′‐bis(diphenylphosphinoyl)‐BINOL (**3**) or (__R__)‐3,3′‐bis(diphenylt