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Conjugate addition of lithium diorganocuprate reagents to the enol tosylate of a 1,2-diketone

✍ Scribed by Jeffrey A. Charonnat; Anna L. Mitchell; Bartholomew P. Keogh

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 207 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)94542-8

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✦ Synopsis

The conjugate addition of lithium diorganocupmte reagents to the enol tosylate of 1,2cyclohexanedione has been investigated. The intermediate enolates eliminatepara-toluenesulfiiate ion to generate the alkylated 1,2-dicarbonyl system.

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