✦ LIBER ✦

A computational study of the 1,4-addition of lithium enolates to conjugated carbonyl compounds.

✍ Scribed by Anna Bernardi; Anna Maria Capelli; Angiolina Comotti; Cesare Gennari; Carlo Scolastico

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 264 KB
Volume: 32
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)74897-0

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Mechanism of Remote Conjugate Addition o

Mechanism of Remote Conjugate Addition of a Lithium Organocuprate to a Polyconjugated Carbonyl Compound

✍ Naohiko Yoshikai; Tatsuya Yamashita; Eiichi Nakamura 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB 👁 2 views

Conjugate addition [1] of a nucleophile to a polyconjugated carbonyl compound is an intriguing reaction as it can potentially result in CÀC bond formation at one of the remote carbon atoms. In many cases, however, the regioselectivity may be poor, unpredictable, or condition-dependent, and the origi

Mechanism of Remote Conjugate Addition o

Mechanism of Remote Conjugate Addition of a Lithium Organocuprate to a Polyconjugated Carbonyl Compound

✍ Naohiko Yoshikai; Tatsuya Yamashita; Eiichi Nakamura 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB 👁 1 views

Conjugate addition of lithium diorganocu

Conjugate addition of lithium diorganocuprate reagents to the enol tosylate of a 1,2-diketone

✍ Jeffrey A. Charonnat; Anna L. Mitchell; Bartholomew P. Keogh 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 207 KB

The conjugate addition of lithium diorganocupmte reagents to the enol tosylate of 1,2cyclohexanedione has been investigated. The intermediate enolates eliminatepara-toluenesulfiiate ion to generate the alkylated 1,2-dicarbonyl system.

ChemInform Abstract: Conjugate Addition

ChemInform Abstract: Conjugate Addition of Lithium Enolates to Aromatic Carbonyl Compounds Complexed with Aluminum Tris(2,6-diphenylphenoxide) (ATPH).

✍ Susumu Saito; Toshihiko Sone; Kazuto Shimada; Hisashi Yamamoto 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Addition of the Lithium Derivatives of 4

Addition of the Lithium Derivatives of 4-Alkyl-3-morpholinones to Carbonyl Compounds

✍ Dobrev, Alexander ;Nechev, Ljubomir ;Ivanov, Christo 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

A theoretical study of malononitrile add

A theoretical study of malononitrile addition to carbonyl compounds

✍ S. El-Taher 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB 👁 2 views

The nucleophilic addition of the malononitrile anion MN to formaldehyde was studied theoretically by the AM1 semiempirical MO method. The addition is found to be endothermic with a late productlike transition state on the reaction coordinate. Additions of MN y to a series of carbonyl compounds were