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Addition of the Lithium Derivatives of 4-Alkyl-3-morpholinones to Carbonyl Compounds

โœ Scribed by Dobrev, Alexander ;Nechev, Ljubomir ;Ivanov, Christo

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
304 KB
Volume
1989
Category
Article
ISSN
0947-3440

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โœ Amos B. Smith III; Robert M. Scarborough Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

Although it is now generally accepted that lithium dienolates undergo near exclusive alkylation at the a rather than the y carbon, 1 we will demonstrate in this letter that, at least, for some 8-alkoxy-a,@-unsaturated carbonyl compounds, subtle structural features can markedly effect the a-selectivi