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Mechanism of Remote Conjugate Addition of a Lithium Organocuprate to a Polyconjugated Carbonyl Compound

โœ Scribed by Naohiko Yoshikai; Tatsuya Yamashita; Eiichi Nakamura


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
350 KB
Volume
44
Category
Article
ISSN
0044-8249

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๐Ÿ“œ SIMILAR VOLUMES


Mechanism of Remote Conjugate Addition o
โœ Naohiko Yoshikai; Tatsuya Yamashita; Eiichi Nakamura ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 350 KB ๐Ÿ‘ 2 views

Conjugate addition [1] of a nucleophile to a polyconjugated carbonyl compound is an intriguing reaction as it can potentially result in Cร€C bond formation at one of the remote carbon atoms. In many cases, however, the regioselectivity may be poor, unpredictable, or condition-dependent, and the origi

A theoretical study of malononitrile add
โœ S. El-Taher ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 173 KB ๐Ÿ‘ 2 views

The nucleophilic addition of the malononitrile anion MN to formaldehyde was studied theoretically by the AM1 semiempirical MO method. The addition is found to be endothermic with a late productlike transition state on the reaction coordinate. Additions of MN y to a series of carbonyl compounds were