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ChemInform Abstract: anti-1,3-Diols by Addition of Dialkylzinc Reagents to 4-Acetoxy-1,3-dioxanes.

โœ Scribed by Noel A. Powell; Scott D. Rychnovsky

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diastereoselective
ChemInform Abstract: Diastereoselective Synthesis of Polypropionates: Cationic Couplings of 4-Acetoxy-1,3-dioxanes with Crotyl-Metal Reagents.
โœ S. D. RYCHNOVSKY; C. J. SINZ ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB

Diastereoselective Synthesis of Polypropionates: Cationic Couplings of 4-Acetoxy-1,3-dioxanes with Crotyl-Metal Reagents. -Cationic couplings of 4-acetoxy-1,3-dioxanes with allylic metal reagents are investigated. The diastereoselectivity shows marked dependence on the Lewis acid, the reactivity o