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Addition and metallation in the reaction of n-butyl-lithium with 2-ferrocenylpyridine

✍ Scribed by D.J. Booth; B.W. Rockett

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 196 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90986-9

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✦ Synopsis

A number of N,N-dialhylarylmethylamiues including beasyldimethylamine (2), dimethylaminomethylferrocene (I), (3), N-(ferrocenylmethyl)piperidine (4), and N-(ferrocenylmethyl)pyrrolidine (4), have been shown to undergo specific 2-lithiation by n-butyl-lithium in ether-herane. Thus the amine (I) gave the lithio-amine (I') and

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