Polymerization of tert-butyl acrylate in the presence of n-butyl lithium and titanium tetrachloride
β Scribed by E.A.H. Hopkins; M.L. Miller
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 243 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0032-3861
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Miniemulsion copolymerization of styrene/__n__βbutyl acrylate was investigated as a means of encapsulating hydrophilic titanium dioxide (TiO~2~) in a filmβforming polymer. Dispersion studies of the TiO~2~ were first carried out to determine the choice of stabilizer, its concentration, a
The photolysis of n-butyl-(N,N-diethyl dithiocarbamyl)propionate (RTC), an initiator for "livingΓ free radical polymerizations, has been investigated in order to elucidate the mechanism of these polymerizations. The photolysis yields tetraethylthiuram disulphide (TED), and its degradation products,
ln of the rate of polymerization vs [DDT]/[BA] for homopolymerization of butyl acrylate at 40, 50 and 60 8C, in a 3 mol/ L benzene solution and with [AIBN] = 5 6 10 -3 mol/L.
## Abstract __n__βButyl acrylate (BA) starvedβfeed solution semibatch experiments with varying final polymer content and monomer feed times were carried out at 138βΒ°C. A full mechanistic model of the system implemented in Predici includes intermolecular chain transfer to polymer and macromonomer pr
The batch emulsion polymerization of butyl acrylate in the presence of sodium lauryl sulphate as emulsifier and potassium persulphate as initiator was investigated. The effects of emulsifier concentration, initiator concentration, and monomer/water ratio on the kinetic features were studied. The kin