✦ LIBER ✦

Addition and lithiation reactions of N-(1-phenylalkylidene)anilines with lithium dialkylamides

✍ Scribed by Lucjan Strekowski; Steven Patterson; Marek T. Cegla; Roman L. Wydra; Agnieszka Czarny; Donald B. Harden

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 335 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93740-2

No coin nor oath required. For personal study only.

✦ Synopsis

Lithium diisopropylamide undergoes an addition reaction to the methyleneamino moiety of the title Schiffs bases substituted with a cyano group at the ortho or parn position of the aniline, but mediates tautomerization of the unsubstituted and metasubstituted derivatives into secondary enamines.

Only the tautomerization is observed for lithium 2,2,6,6-tetramethylpiperidide-mediated reactions.

📜 SIMILAR VOLUMES

Addition and metallation in the reaction

Addition and metallation in the reaction of n-butyl-lithium with 2-ferrocenylpyridine

✍ D.J. Booth; B.W. Rockett 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 196 KB

A number of N,N-dialhylarylmethylamiues including beasyldimethylamine (2), dimethylaminomethylferrocene (I), (3), N-(ferrocenylmethyl)piperidine (4), and N-(ferrocenylmethyl)pyrrolidine (4), have been shown to undergo specific 2-lithiation by n-butyl-lithium in ether-herane. Thus the amine (I) gave

Highly Regioselective, Three-Component R

Highly Regioselective, Three-Component Reactions of Diazoacetates with Anilines and β,γ-Unsaturated α-Keto Esters: 1,2-Addition versus 1,4-Addition

✍ Yingguang Zhu; Changwei Zhai; Liping Yang; Wenhao Hu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 423 KB 👁 1 views

ChemInform Abstract: Highly Regioselecti

ChemInform Abstract: Highly Regioselective, Three-Component Reactions of Diazoacetates with Anilines and β,γ-Unsaturated α-Keto Esters: 1,2-Addition versus 1,4-Addition.

✍ Yingguang Zhu; Changwei Zhai; Liping Yang; Wenhao Hu 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 45 KB 👁 2 views

## Abstract The course of the reaction is highly dependent on the electronic nature of the diazoacetates.

ChemInform Abstract: Unusual Reactions o

ChemInform Abstract: Unusual Reactions of 1-(Alk-1-ynyl)-1-chlorocyclopropanes with Lithium Monoalkylamides.

✍ Konstantin N. Shavrin; Valentin D. Gvozdev; Serafim V. Yurov; Oleg M. Nefedov 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Reactions of the N,N-dialkylpyridylcarbo

Reactions of the N,N-dialkylpyridylcarboxylic amides with lithium amides. Regioselective lithiation of N,N-diisopropylpyridylcarboxylic amides, a useful method for synthesis of 2,3- and 3,4-disubstituted pyridines

✍ Jan Epsztajn; Zbigniew Berski; Jacek Z. Brzeziński; Andrzej Jóźwiak 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 239 KB

Reactions of Stable Amidinate Chlorosily

Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline

✍ Anukul Jana; Ramachandran Azhakar; Sankaranarayana Pillai Sarish; Prinson P. Sam 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 629 KB