Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline
β Scribed by Anukul Jana; Ramachandran Azhakar; Sankaranarayana Pillai Sarish; Prinson P. Samuel; Herbert W. Roesky; Carola Schulzke; Debasis Koley
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 629 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The reactions of __N__β(5,6βdihydro[1]benzoxepino[5,4β __d__]pyrimidinβ4βyl)amidines or its amide oxime derivatives with hydroxylamine hydrochloride gave abnormal cyclization products __via__ a ring cleavage of pyrimidine component accompanied with a ring closure of [1,2,4]oxadiazole.
## Abstract The reactions of __N__β(5,6βdihydro[1]benzothiepino[5,4β__d__]pyrimidinβ4βyl)amidines or its amide oxime derivatives with hydroxylamine hydrochloride under basic condition gave abnormal cyclization products __via__ a ring cleavage of pyrimidine component accompanied with a ring closure