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Addition and abstraction reactions involving trichloromethyl radicals

✍ Scribed by E.C. Kooyman

Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
490 KB
Volume
19
Category
Article
ISSN
0040-4020

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✦ Synopsis

The significance of numerical data derived from Hueckel's classical zero-order M.O. treatment for the interpretation ofreactivities towards CC13 radicals is critically discussed. Attention is called to polar and steric effects as the main causes of discrepancies.

πŸ“œ SIMILAR VOLUMES

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The photolysis of carbon tetrachloride in the presence of a number of organosilicon compounds has been investigated in the gas phase. The products obtained from the photolysis experiments were those expected from a chain reaction in which trichloromethyl radicals abstract hydrogen atoms from the org

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The preceding paper describes the reanalysis by Kerr and Parsonage (following discussions with one of us, H.W.S.) of some of our published work. We are grateful to Dr. Kerr for communicating their conclusions to us. We agree in principle with their analysis, and the present communication is to repor