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Acylation of alkynes by cationoid reagents with the formation of cyclopent-2-enone derivatives

✍ Scribed by A.A. Schegolev; W.A. Smit; G.V. Roitburd; V.F. Kucherov

Book ID
104243032
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
243 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

We have recently described the successful use of carbocationic reagents in electiophilic additions to the triple bond and demonstrated that vinyl cations, presumably formed as intermediates in these reactions, could be trapped even by such poor nucleophilic solvents as nitromethane /I/ or chlorobenzene /2/. These results encouraged us to undertake a more thorough investigation of the reactivity of these intermediates in different solvent systems.

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