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Formation of 1,2-disubstituted adamantanes upon the acylation of methylacetylene by derivatives of 1-adamantanecarboxylic acid

โœ Scribed by M. I. Kanishchev; V. A. Smit; A. A. Shchegolev; R. Caple

Book ID
112438826
Publisher
Springer
Year
1977
Tongue
English
Weight
58 KB
Volume
26
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

The formation of 1,2-disubstituted adama
The formation of 1,2-disubstituted adamantanes via the acylation of alkynes with 1-adamantanoyl derivatives
โœ M.I. Kanischev; W.A. Smit; A.A. Schegolev; R. Caple ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

## Earlier we demonstrated that a 1,5-hydride shift readily occurs in the vinyl cation intermediate formed in the course of acylation of alkynes with acylium salts.' This paper deals with the application of this process for the preparation of a series of 1,2\_disubstituted adamantanes,