The formation of 1,2-disubstituted adamantanes via the acylation of alkynes with 1-adamantanoyl derivatives

✍ Scribed by M.I. Kanischev; W.A. Smit; A.A. Schegolev; R. Caple

• Book ID: 104245616
• Publisher: Elsevier Science
• Year: 1978
• Tongue: French
• Weight: 200 KB
• Volume: 19
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)94563-0

✦ Synopsis

Earlier we demonstrated that a 1,5-hydride shift readily occurs in the vinyl cation intermediate formed in the course of acylation of alkynes with acylium salts.'

This paper deals with the application of this process for the preparation of a series of 1,2_disubstituted adamantanes,