## Abstract Polybenzopinacols resulting from the photocondensations of __p__,__p__โฒโdibenzoyldiphenyl ether, __p__,__p__โฒโdibenzoyldiphenylmethane, and __p__,__p__โฒโdibenzoylโ1,2โdiphenylethane were rearranged in sulfuric acidโdioxane solutions. The inherent viscosities of the polybenzopinacolones
โฆ LIBER โฆ
Acid-catalyzed rearrangements in a crowded aromatic system
โ Scribed by Kwo-Hrong Lai; Bernard Miller
- Book ID
- 104248161
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 190 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The presence of a &-butyl group ortho to another substituent on an aromatic ring causes appreciable steric strain in the molecule. The strain energy in o-t-butylto--luene has been estimated to be around 4-6 kcal./mole,1,2 while the presence of a se-
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