Acid-catalyzed Rearrangement of Some Aromatic Ketones1
โ Scribed by Mosher, William A.; Huber, Melvin L.
- Book ID
- 115313384
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 506 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
2-(4-Ketoalkyl)cyclopentanones, when subjected to the action of 1 M H 2 SO 4 at reflux, undergo ring cleavage and formation reactions to give 4-(1-cyclopentenyl)butanoic acids. When the starting ring is six-membered instead, a bicyclic enone results. Mechanistic discussion and some experimental test
## Abstract Polybenzopinacols resulting from the photocondensations of __p__,__p__โฒโdibenzoyldiphenyl ether, __p__,__p__โฒโdibenzoyldiphenylmethane, and __p__,__p__โฒโdibenzoylโ1,2โdiphenylethane were rearranged in sulfuric acidโdioxane solutions. The inherent viscosities of the polybenzopinacolones