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Disproportionation in acid-catalyzed ketone rearrangements

โœ Scribed by Ikuo Ookuni; Arthur Fry

Book ID
104212591
Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
164 KB
Volume
3
Category
Article
ISSN
0040-4039

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Acid-catalyzed aldehyde-ketone rearrange
Acid-catalyzed aldehyde-ketone rearrangements in the gas phase. Cyclopentane- and cyclohexanecarboxaldehyde.
โœ Pierluigi Giacomello; Adriano Pizzabiocca; Gabriele Renzi; Maurizio Speranza ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

Protonation by gaseous Hi, CnHi (n=1,2), s-C3HG and t-C H+ 49 cations promotes rearrangement of cyclopentane-and cyclohexanecarboxaldehyde to cyclohexanone and cyclo~entylmethyl ketone, respectively. The reaction was investigated by radiolytic and mass spectrometric methods. The mechanism of the aci