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Acid-catalyzed nitramine rearrangement. IV. Influence of aromatic ring substituents on rearrangement rate

✍ Scribed by White, William North.; Klink, Joel R.

Book ID
120475348
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
613 KB
Volume
35
Category
Article
ISSN
0022-3263

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## Abstract The acid catalyzed rearrangement of 1‐bromotetracyclo[4.3.0.0^2.5^0^3.8^]nonan‐4‐one 1b has been studied. With aqueous HBr, the exclusive formation of 2,7‐dibromotricyclo[4.2.1.0^3.7^]‐nonan‐4‐one **4b** was observed. This structure was established by X‐ray analysis. The divergency in b