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Acetatobis(1,10-phenanthroline)­zinc(II) tetrafluoroborate

✍ Scribed by Rodrigues, B. L.

Book ID
104482299
Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
152 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Zn(C 2 H 3 O 2 )(phen) 2 ]BF 4 , where phen is 1,10-phenanthroline (C 12 H 8 N 2 ), crystallizes in the monoclinic space group P2 1 /n. Zinc is in a general crystallographic position and is coordinated by one acetate and two phenanthroline ligands in an approximate mm2 point-group symmetry. The two ZnÐO bond distances are similar to each other, as are the ZnÐN bond distances.

📜 SIMILAR VOLUMES

(4,7-Di­methyl-1,10-phenanthroline)­bis­
(4,7-Di­methyl-1,10-phenanthroline)­bis­(pyrroline­di­thio­carbamato)­zinc(II)
✍ Guo, Tengwen ;Lai, Chian Sing ;Tan, Xi Jie ;Teo, Chin Seng ;Tiekink, Edward R. T 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(1,10-phenanthroline)(3-sulfonatobenz
Bis(1,10-phenanthroline)(3-sulfonatobenzoato)zinc(II) trihydrate
✍ Zhang, Li-Ping ;Zhu, Long-Guan 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 202 KB

In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand o