The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H,O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorpti
Absolute rate constants for the hydroxyl radical reactions with ethane, furan, and thiophene at room temperaturea)
β Scribed by Lee, J. H.
- Book ID
- 111922567
- Publisher
- American Institute of Physics
- Year
- 1982
- Tongue
- English
- Weight
- 580 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.444367
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21
## Abstract The absolute rate constants for the reactions of NH~2~ radicals with ethyl, isopropyl, and __t__βbutyl radicals have been measured at 298 K, using a flash photolysisβlaser resonance absorption method. Radicals were generated by flashing ammonia in the presence of an olefin. A new measur