Rate Constants for the Reactions of Hydroxyl Radical with Several Alkanes, Cycloalkanes, and Dimethyl Ether
โ Scribed by DeMore, W. B.; Bayes, K. D.
- Book ID
- 121260934
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 77 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Absolute rate coeficients for the reactions of the hydroxyl radical with dimethyl ether i k , ) and diethyl ether ( k 2 ) were measured over the temperature range 295-442 K. The rate coefficient data, in the units cm3 molecule s-l, were fitted to the Arrhenius equationsk,(T) = (1.04 2 0.10) x 10-"ex
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21