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Rate constants for reactions of the hydroxyl radical with several partially fluorinated ethers

✍ Scribed by Zhang, Z.; Saini, R. D.; Kurylo, M. J.; Huie, R. E.

Book ID: 127292389
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 563 KB
Volume: 96
Category: Article
ISSN: 0022-3654
DOI: 10.1021/j100202a045

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Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21