✦ LIBER ✦

Theoretical study on rate constants for the reactions of CF3CH2NH2(TFEA) with the hydroxyl radical at 298

✍ Scribed by Mishra, Bhupesh Kumar; Chakrabartty, Arup Kumar; Deka, Ramesh Chandra

Book ID: 120430586
Publisher: Springer-Verlag
Year: 2013
Tongue: English
Weight: 365 KB
Volume: 19
Category: Article
ISSN: 1610-2940
DOI: 10.1007/s00894-013-1762-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Rate constants for the reactions of the

Rate constants for the reactions of the hydroxyl radical with CHF2CF2CF2CHF2 and CF3CHFCHFCF2CF3

✍ Z. Zhang; R.D. Saini; M.J. Kurylo; R.E. Huie 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 383 KB

Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21

Rate constant for the reaction of OH rad

Rate constant for the reaction of OH radical with HFC-365mfc (CF 3 CH 2 CF 2 CH 3 )

✍ Mellouki, Abdelwahid; Téton, Sophie; Le Bras, Georges 📂 Article 📅 1995 🏛 American Geophysical Union 🌐 English ⚖ 295 KB

Rate constants for the reactions of OH r

Rate constants for the reactions of OH radicals with CH3OCF2CF3, CH3OCF2CF2CF3, and CH3OCF(CF3)2

✍ K. Tokuhashi; A. Takahashi; M. Kaise; S. Kondo; A. Sekiya; S. Yamashita; H. Ito 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 1 views

The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine

Rate constants for the reaction of CF3O

Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K

✍ Christina Kelly; Jack Treacy; Howard W. Sidebottom; Ole John Nielsen 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 523 KB

Rate constant ratios of the reactions of CFsO radicals with a number of hydrocarbons have been determiued at 298 + 2 K and atmospheric pressure using a relative rate method. Using a previously determined value k(CF,O+ CsHs) = I .2 x lo-i2 cm3 molecule-' s-i these rate constant mtios,provide estimate

Rate constants for the reactions of OH r

Rate constants for the reactions of OH radicals with CF3OCF=CF2 and CF3CF=CF2

✍ Kazuaki Tokuhashi; Akifumi Takahashi; Masahiro Kaise; Shigeo Kondo; Akira Sekiya 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 152 KB

Theoretical study and rate constant calc

Theoretical study and rate constant calculation for reaction of CF3CH2OH with OH

✍ Ying Wang; Jing-Yao Liu; Ze-Sheng Li; Li Wang; Chia-Chung Sun 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 357 KB 👁 2 views

## Abstract The reaction mechanism of CF~3~CH~2~OH with OH is investigated theoretically and the rate constants are calculated by direct dynamics method. The potential energy surface (PES) information, which is necessary for dynamics calculation, is obtained at the B3LYP/6‐311G (d, p) level. The si