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Absolute configurations of enantiomeric K-region cis-5,6-dihydrodiols of 12-methylbenz[A] anthracene and 7-bromo-12-methylbenz[A] anthracene

✍ Scribed by Shen K. Yang; Mohammad Mushtaq; Henri B. Weems; Peter P. Fu

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
266 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

The absolute configurations of enantiomeric 7-bromo-12lpethylbenz[a]anthracene cis 5,6-dihydrodiols (3) were determined by exciton chirality circular dichroism method, The absolute configurations of enantiomeric 12-methylbenz[a]anthracene c&-5,6-dihydrodiols (1) were determined by debromination of enantiomeric 3 of known absolute stereochemistry.

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