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Absolute configuration of endo-cis-bicyclo[3.3.0]oct-7-en-2-ol and specific rotation of 3-oxocyclopentaneacetic acid

โœ Scribed by Kuritani, Hiroko; Takaoka, Yoshiko; Shingu, Keiji

Book ID
126037177
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
447 KB
Volume
44
Category
Article
ISSN
0022-3263

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โœ Emanuela Marotta; Ilaria Pagani; Paolo Righi; Goffredo Rosini; Valerio Bertolasi ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 596 KB

Single crystal X-ray diffraction analysis of compounds A, B and, C helped us to assign the absolute configurations of the enantiomers of the bicyclo[3.2.0]hept-3-en-6-endo-ols 4-6. These bicyclic alcohols were easily obtained by: (i) stereoselective reductions of the bicyclo[3.2.0]hept-3-en-6-ones 1